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Ah, classic HYSYS hiccup, yeah NaHS ain't in the built-in list, you can try adding it as a hypothetical component or switch to a more reactive property package, that's where folks slip up
NaHS isnt a predefined component in HYSYS, so thats why it doesn't show up. The easiest way is to model it as a pseudo-component or use a combination of Na+ and HS- species in an electrolyte package, making sure to define the reaction NaOH + H2S ⇌ NaHS + H2O in the reactions section.